I would not recommend anyone spraying an engine with a starter fluid especially if they are unfamiliar with what to look for, also if there was any spark leakage (even slight) from a coil or wire you could have a potential explosion. I generally use a (certain type) of brake clean which wont take paint off surfaces or melt certain types of rubber such as most carb clean, but like I said if not known what doing then test is pointless.
Was the battery unhooked when you installed the horns? possibly something reset after hookup?, lots of maybes and I am not super familiar with your situation or going to pretend to be. Is one of the boards technically gifted members close to you, such as Meyagi? Having them look at it would probably save time and aggrevation.