Hmm, well, the normal difference between the price for 91 and 93 is $0.10/gallon, so unless the octane boost costs less than $1.20 and raises the octane rating of the whole tank up to 93, sh'aint worth it.
I used to put a thing of that stuff through at each oil change on one of my Saabs...don't know if it really did anything but make me feel good.